Axelle Barnet, PhD student of the LGP2, recently defended her doctoral thesis: "Understanding of the ageing phenomena occurring in electrotechnical papers in power transformers and research of industrial solutions" at the University of Grenoble, France.
Power transformers are expensive devices and the degradation of the cellulosic insulation paper contributes to limiting the transformer life expectancy. This work studies the kinetic degradation of two electrotechnical papers during accelerated ageing trials in mineral oil: one standard paper and one Thermally Upgraded paper (TU) containing an additive.
The degradation of the standard paper, measured via the cellulose viscometric degree of polymerisation (DPv), follows a first order kinetic model and the calculated activation energy is close to activation energy reported for the acid hydrolysis of cellulose in the literature. The TU paper behaves differently since the additive slows the paper degradation, and none of the tested kinetics models succeed to model experimental data. A deeper study of the additive reaction mechanism confirms and completes the hypotheses presented in the literature.
Moreover, some mechanical characterizations of aged papers highlight a correlation between the cellulose DPv and the double fold resistance of the paper. Thereafter, it has been discussed if the presence of lignin in paper presents a protective effect on cellulose and it has been shown that it leads to the production of methanol (used as a marker of paper degradation to monitor power transformers).
Finally, a new protective solution on the paper surface, gave encouraging results, particularly in terms of paper mechanical strength properties preservation.